Jawaharlal Nehru Centre for Advanced Scientific Research - An Autonomous Institution

Theoretical Sciences Unit Seminar - 8 August 2022

Speaker Event

Speaker: Dr. Dwaipayan Chakrabarti

Affiliation: University of Birmingham, UK

Date: 08 August 2022 (Monday)

Time: 11:00 AM

Tea/Coffee: 10:45 AM

Venue: Kanada Auditorium, JNCASR

Title: Social Distancing in Colloidal Crystals

Abstract:

Colloidal open crystals — sparsely populated periodic structures, comprising low-coordinated colloidal particles — are attractive targets for self-assembly because of their variety of applications, for example, as photonic materials, phononic and mechanical metamaterials, as well as porous media [1-4].

Colloidal particles in their primitive form offer short-range isotropic interactions and thus tend to form close-packed structures. Despite remarkable advances over the last two decades in the synthesis of designer colloidal particles, interacting via anisotropic and/or specific interactions [5,6], programming self-assembly of colloidal particles into open crystals has proved elusive because of issues concerning both thermodynamics and kinetics.

In this presentation, I will establish a number of rationally designed self-assembly schemes for patchy particles with decorated surfaces that address these issues to efficiently yield in silico a variety of colloidal open crystals, especially those much sought-after as photonic crystals [7-10]. In particular, I will demonstrate how the selection of certain even-member rings formed along the assembly pathways is critical to improving the kinetics of self-assembly of these colloidal open crystals [8-10]. I will discuss how our design rules, while hewing closely to current experimental constraints, alleviate issues that have impeded the success of colloidal self-assembly as a scalable fabrication route to photonic crystals [9].

References:

  • [1] X. Mao, Q. Chen and S. Granick, Nat. Mater. 2013, 12, 217.
  • [2] M. He, J. P. Gales, É. Ducrot, Z. Gong, G.-R. Yi, S. Sacanna and D. J. Pine, Nature, 2020, 585, 524.
  • [3] K. Aryana and M. B. Zanjani, J. Appl. Phys., 2018, 123, 185103.
  • [4] X. Mao and T. C. Lubensky, Annu. Rev. Condens. Matter Phys., 2018, 9, 413.
  • [5] T. Hueckel, G. M. Hocky and S. Sacanna, Nat. Rev. Mater., 2021, 6, 1053.
  • [6] W. B. Rogers, W. M. Shih and V. N. Manoharan, Nat. Rev. Mater., 2016, 1, 16008.
  • [7] D. Morphew, J. Shaw, C. Avins and D. Chakrabarti, ACS Nano, 2018, 12, 2355.
  • [8] A. B. Rao, J. Shaw, A. Neophytou, D. Morphew, F. Sciortino, R. L. Johnston and D. Chakrabarti, ACS Nano, 2020, 14, 5348.
  • [9] A. Neophytou, V. N. Manoharan and D. Chakrabarti, ACS Nano, 2021, 15, 2668.
  • [10] A. Neophytou, D. Chakrabarti and F. Sciortino, Proc. Natl. Acad. Sci. USA, 2021, 118, e2109776118.
Event Date :
Event End Date :
Place of the event :
JNCASR
Organised by :
Theoretical Sciences Unit
Other Venue :
Sponsored Event :
High tea time :
Organising Team :
Prof. Srikanth Sastry