Ferroelectricity and a 1/3-Magnetization Plateau in the Polar Magnet LiFeV2O7 with Fe3+ Ions in a Twisted Diamond Chain

Ferroelectricity and a 1/3-Magnetization Plateau in the Polar Magnet LiFeV2O7 with Fe3+ Ions in a Twisted Diamond Chain

We investigated the thermodynamic properties and spin exchanges of the polar magnet LiFeV2O7 through experiments and density functional theory calculations. LiFeV2O7 crystallizes in a polar monoclinic Cc structure, where Fe3+ (S = 5/2) ions form diamond chains along the [101] direction, each surrounded by four neighboring chains. The compound undergoes long-range antiferromagnetic ordering at TN ≈ 5 K, which decreases under an external magnetic field. Below TN, it exhibits multiferroic behavior, and a 1/3-magnetization plateau above a critical field of 4.3 T. Neutron diffraction measurement at 1.5 K reveals a collinear magnetic structure with k = (0, 1, 0) with unequal spin moments on monomer and dimer sites of the diamond chains (3.41(1) vs 1.56(1) μB). These unique magnetic properties stem from strongly antiferromagnetic dimer spin exchange and weakly antiferromagnetic dimer–monomer spin exchanges. This results in a small energy gap between the magnetic ground and excited states below TN and induces thermal spin fluctuations at the monomer and dimer sites reducing their moments. The further reduction of the moment at the dimer sites is ascribed to quantum spin fluctuations of the dimer sites.

Magnetic field-dependent magnetization and magnetic structure of LiFeV2O7 at 1.5 K with magnetic moments plotted on the Fe atoms in the inset; Change in polarization (ΔP) as a function of temperature obtained from depolarization peak of dc-bias current.